Engineering Thermodynamics: Unit V: Gas Mixtures and Thermodynamic Relations

Energy Equations

Internal Energy, Enthalpy Relations | Thermodynamics

Mainly, the energy equations are internal energy, enthalpy and entropy.

ENERGY EQUATIONS

Mainly, the energy equations are internal energy, enthalpy and entropy.


1. Internal Energy

We know that the internal energy

du = Tds - pdv

Let the entropy (s) is the function of temperature (T) and specific volume (v).


From equation (5.66), the internal energy in terms of measurable properties such as p, v, T and Cv can be determined.


2. Enthalpy Relations

We know that from first law of thermodynamics

Enthalpy, dh = Tds + vdp [from equation (5.57)]

Let the entropy (s) is the function of temperature (T) and specific volume (v).

i.e. s = f(T, p)


Substituting ds value in dh equation,


The above equation (5.68) appears in the form of dh = CpdT + Constant

So, Cp can be written as


From Maxwell equations,


From equation (5.70), the enthalpy in terms of measurable properties such as p, v, T and Cp can be calculated.

Engineering Thermodynamics: Unit V: Gas Mixtures and Thermodynamic Relations : Tag: : Internal Energy, Enthalpy Relations | Thermodynamics - Energy Equations


Engineering Thermodynamics: Unit V: Gas Mixtures and Thermodynamic Relations



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Engineering Thermodynamics

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